Comparing measurement values yourself against a known reference is called self-monitoring. For example, temperature and relative humidity can easily be checked this way.
When it comes to temperature, a “known reference” can easily be created at 0 °C by using an ordinary thermos flask. Fill it with as much ice as possible, then add water to fill it completely. Let it sit in the refrigerator for about 20 minutes. Stir the ice bath, and place the sensor tip in the center of the thermos.
Self-monitoring of humidity instruments can be done using so-called humidity salts. These are containers with a salt solution that provide a specific relative humidity level. A common option is to use a standard set with two containers at 11.3% and 75.3% RH. To perform the check, insert the humidity sensor into the container using a clamping screw in the lid. The sensor must remain there for a specified period (see the instructions provided with the containers).
An important thing to remember during any type of calibration—including self-monitoring—is that the instrument or sensor needs time to adapt to its surroundings. If you bring a cold instrument in from outside and immediately take a reading at room temperature, you will get a measurement error. A good rule of thumb is to let the instrument or sensor rest overnight before calibration.